This paper is concerned with measurement of airflow in ducts using an active (pumped) sampling system. The system is capable of sampling tracer gases using either tubes packed with adsorbent or sample bags. A perfluorocarbon tracer (PFT) was injected into the ducts using thermostatically-controlled heating blocks. The samples were collected and analysed using a thermal desorber/gas analyser system. Laboratory and field testing of airflow in ducts was carried out. A large office building was studied for measurements of ventilation rate, ventilation efficiency and air quality. A questionnaire was also completed by office staff in order to assess air quality and thermal comfort.