An experimental method for the determination of the internal diffusion coefficient (D) and partition coefficient (ke) of volatile organic compounds (VOCs) is developed for dry building materials (such as carpet, vinyl flooring. plywood, etc.). The method is used to determine D and k0 for four VOCs (toluene, nonane. decane, and undecane ) through the backing material of a carpet specimen, for four vocs (ethylbenzene, nonane, decane, and undecane) through a floor tile specimen, and three vocs (cyclohexene, ethylbenzene. and decanc) through a plywood specimen.